Kate channels her inner Bond girl as royals arrive for No Time To Die World Premiere

Kate Middleton has channelled her inner Bond girl for the World Premiere of No Time To Die at London's Royal Albert Hall.

The Duchess of Cambridge stunned in a gold cape gown by British designer (and one of her favourites) Jenny Packham for the glittering occasion.

The mum-of-three joined husband Prince William and in-laws Prince Charles and the Duchess of Cornwall on Tuesday (Wednesday AEST) for the red carpet event celebrating the 25th movie in the 007 film franchise.

BAFTA President the Duke of Cambridge looked dapper in a velvet jacket tuxedo, while Prince Charles opted for a traditional tux.

Camilla looked lovely in a powder blue floor-length gown with beading detail by British designer Bruce Oldfield.

The Cambridges arrived first and chatted away at the start of the red carpet with the movie's producers Barbara Broccoli and Michael G. Wilson.

There were kisses on both cheeks when the Prince of Wales and Duchess of Cornwall arrived before the new royal awesome foursome walked up the steps and paused for photos.

Once inside, the royals were introduced to the film's stars in attendance, including Daniel Craig, Rami Malek, Ana de Armas, Léa Seydoux and Lashana Lynch.

Also in the royal line-up was actress Phoebe Waller-Bridge, who was one of the movie's writers, as well as brother and sister musicians Billie Eilish and Finneas O'Connell who recorded the movie's theme song together.

Prince Charles, patron of the British Film Institute, had paid a visit to the film's set at Pinewood Studios in London back in June 2019.

No Time To Die will be Daniel Craig's fifth and last outing as the British spy.

Craig also had a very special James Bond moment, recorded especially for the 2012 London Olympic Games Opening Ceremony, alongside Queen Elizabeth.

The royals are attending the world premiere to celebrate members of the armed forces and health care workers, some of whom have been invited to the event as a thanks for their work on the UK's coronavirus response.

The event is also set to benefit charities supporting serving and former members of the three intelligence agencies (the Secret Intelligence Service, the Security Service and GCHQ) along with charities supporting past and present members of the UK Special Forces.